Microporous Metal-Organic Framework Materials for Sensing and Separation of Gas or Solvent Molecules
Description
The present invention introduces a novel metal-organic framework (MOF) and a novel mixed metal-organic framework (M'MOF) for selective gas storage, selective gas sorption and/or separation, selective sensing of chemicals, and catalysis.
Problem
Although thousands of MOFs and M′MOFs have been synthesized and structurally characterized over the past few decades, very few MOFs have been shown to be useful for selective sorption, separation and/or sensing of guest molecules.
Solution
This invention offers superior methods for gas separation by introducing a novel rod packing microporous MOF with repeating unit Zn4(OH)2(1,2,4-BTC)2 which uses open metal sites and a novel M'MOF with repeat unit Zn3(BDC)3[Cu(SalPyCy)] or Zn3(CDC)3[Cu(SalPyCy)] with chiral pores/pockets.
Value Proposition
These technologies presents MOFs exhibits highly selective sorption and separation of gases due to their unique micropore features.
Competitive Advantages
- High capacities & efficient separation and removal of acetylene/ethylene
- Specific recognition and separation of small molecules
- Unique, temperature dependent gas separation capabilities
- Unique sorption isotherms and the highly selective sorption behaviors
- Potential for the reduced cost of production of highly porous metal-organic materials
Status of Development
Seeking commercial partnersIP Status
- Licensing available
- Patent #US8507406B2, US9296773B2
Related Publications
- Xiang, S.; Zhang, Z.; Zhao, C.-G.; Hong, K.; Zhao, X.; Ding, D.-R.; Xie, M.-H.; Wu, C.-D.; Das, M. C.; Gill, R.; Thomas, K. M.; Chen, B.* Rationally Tuned Micropores within Enantiopure Metal-Organic Frameworks for Highly Selective Separation of Acetylene and Ethylene, Nat. Commun. 2011, 2, 204.
- Zhang, Z.; Xiang, S.; Rao, X.; Zheng, Q.; Fronczek, F. R.; Guodong Qian, G.; Chen, B.* A Rod Packing Microporous Metal-Organic Framework with Open Metal Sites for Selective Guest Sorption and Sensing of Nitrobenzene, Chem. Commun. 2010, 46, 7205.
